Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate

The asymmetric unit of the title compound, C(21)H(16)N(4)O(4)·4CH(3)OH, consists of a quarter mol­ecule of tetra­kis­(1-oxidopyridin-2-yl)methane and one methanol solvent mol­ecule. In the crystal, the pyridine N-oxide derivative is located about a fourfold rotoinversion axis and exhibits S (4) symm...

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Autores principales: Matsumoto, Kouzou, Kawashita, Kazuaki, Kannami, Masaki, Oda, Masaji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647381/
https://www.ncbi.nlm.nih.gov/pubmed/26594459
http://dx.doi.org/10.1107/S2056989015016862
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author Matsumoto, Kouzou
Kawashita, Kazuaki
Kannami, Masaki
Oda, Masaji
author_facet Matsumoto, Kouzou
Kawashita, Kazuaki
Kannami, Masaki
Oda, Masaji
author_sort Matsumoto, Kouzou
collection PubMed
description The asymmetric unit of the title compound, C(21)H(16)N(4)O(4)·4CH(3)OH, consists of a quarter mol­ecule of tetra­kis­(1-oxidopyridin-2-yl)methane and one methanol solvent mol­ecule. In the crystal, the pyridine N-oxide derivative is located about a fourfold rotoinversion axis and exhibits S (4) symmetry along the c axis. An inter­molecular O—H⋯O hydrogen bond is observed between the O atom of the pyridine N-oxide and the OH group of the methanol. An inter­molecular C—H⋯O bond is also observed between adjacent pyridine N-oxide rings.
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spelling pubmed-46473812015-11-20 Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate Matsumoto, Kouzou Kawashita, Kazuaki Kannami, Masaki Oda, Masaji Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(21)H(16)N(4)O(4)·4CH(3)OH, consists of a quarter mol­ecule of tetra­kis­(1-oxidopyridin-2-yl)methane and one methanol solvent mol­ecule. In the crystal, the pyridine N-oxide derivative is located about a fourfold rotoinversion axis and exhibits S (4) symmetry along the c axis. An inter­molecular O—H⋯O hydrogen bond is observed between the O atom of the pyridine N-oxide and the OH group of the methanol. An inter­molecular C—H⋯O bond is also observed between adjacent pyridine N-oxide rings. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647381/ /pubmed/26594459 http://dx.doi.org/10.1107/S2056989015016862 Text en © Matsumoto et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Matsumoto, Kouzou
Kawashita, Kazuaki
Kannami, Masaki
Oda, Masaji
Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
title Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
title_full Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
title_fullStr Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
title_full_unstemmed Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
title_short Crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
title_sort crystal structure of tetra­kis­(1-oxidopyridin-2-yl)methane methanol tetra­solvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647381/
https://www.ncbi.nlm.nih.gov/pubmed/26594459
http://dx.doi.org/10.1107/S2056989015016862
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