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Crystal structure of 3a,6,6,9a-tetra­methyl­dodeca­hydro­naphtho­[2,1-b]furan-2-ol

The title compound (common name: sclaral), C(16)H(28)O(2), is a sclareolide derivative, which was synthesized from sclareolide itself. In the mol­ecule, the two six-membered rings, A and B, of the labdane skeleton adopt chair conformations and the five-membered O-containing heterocyclic ring C displ...

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Detalles Bibliográficos
Autores principales: Shi, Xin-Wei, Li, Sheng-Kun, Li, Dang-Dang, Lu, Qiang-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647384/
https://www.ncbi.nlm.nih.gov/pubmed/26594436
http://dx.doi.org/10.1107/S2056989015016370
Descripción
Sumario:The title compound (common name: sclaral), C(16)H(28)O(2), is a sclareolide derivative, which was synthesized from sclareolide itself. In the mol­ecule, the two six-membered rings, A and B, of the labdane skeleton adopt chair conformations and the five-membered O-containing heterocyclic ring C displays an envelope conformation, with the methine C atom of the fused C—C bond as the flap. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming chains propagating along [100].