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Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride

In the title mol­ecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)...

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Detalles Bibliográficos
Autores principales: Kandhaswamy, Abirami, Meena, K.S., Deepa, S., Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647393/
https://www.ncbi.nlm.nih.gov/pubmed/26594461
http://dx.doi.org/10.1107/S2056989015016916
Descripción
Sumario:In the title mol­ecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked via N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C—H⋯π inter­actions, forming a two-dimensional supra­molecular network.