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Crystal structure of [(2S,3R)-3-hydroxy-3-phenylbutan-2-yl]pyrrolidinium chloride
In the title molecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647393/ https://www.ncbi.nlm.nih.gov/pubmed/26594461 http://dx.doi.org/10.1107/S2056989015016916 |
Sumario: | In the title molecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked via N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C—H⋯π interactions, forming a two-dimensional supramolecular network. |
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