Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride

In the title mol­ecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)...

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Autores principales: Kandhaswamy, Abirami, Meena, K.S., Deepa, S., Murugavel, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647393/
https://www.ncbi.nlm.nih.gov/pubmed/26594461
http://dx.doi.org/10.1107/S2056989015016916
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author Kandhaswamy, Abirami
Meena, K.S.
Deepa, S.
Murugavel, S.
author_facet Kandhaswamy, Abirami
Meena, K.S.
Deepa, S.
Murugavel, S.
author_sort Kandhaswamy, Abirami
collection PubMed
description In the title mol­ecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked via N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C—H⋯π inter­actions, forming a two-dimensional supra­molecular network.
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spelling pubmed-46473932015-11-20 Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride Kandhaswamy, Abirami Meena, K.S. Deepa, S. Murugavel, S. Acta Crystallogr E Crystallogr Commun Data Reports In the title mol­ecular salt, C(14)H(22)NO(+)·Cl(−), the pyrrolidinium ring adopts a twisted conformation about one of the N—C bonds. It is oriented at a dihedral angle of 42.0 (1)° with respect to the benzene ring. The torsion angle for the central N—C—C—C(ar) (ar = aromatic) linkage is 163.74 (15)°. In the crystal, the components are linked via N—H⋯Cl and O—H⋯Cl hydrogen bonds, forming zigzig chains along the b-axis direction. These chains are connected along the c axis by very weak C—H⋯π inter­actions, forming a two-dimensional supra­molecular network. International Union of Crystallography 2015-09-17 /pmc/articles/PMC4647393/ /pubmed/26594461 http://dx.doi.org/10.1107/S2056989015016916 Text en © Kandhaswamy et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kandhaswamy, Abirami
Meena, K.S.
Deepa, S.
Murugavel, S.
Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
title Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
title_full Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
title_fullStr Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
title_full_unstemmed Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
title_short Crystal structure of [(2S,3R)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
title_sort crystal structure of [(2s,3r)-3-hy­droxy-3-phenyl­butan-2-yl]pyrrolidinium chloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647393/
https://www.ncbi.nlm.nih.gov/pubmed/26594461
http://dx.doi.org/10.1107/S2056989015016916
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