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Crystal structure of (E)-2-(4-chlorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one: a second monoclinic polymorph
The title compound, C(17)H(13)ClO, is the second monoclinic polymorph to crystallize in the space group P2(1)/c. The first polymorph crystallized with two independent molecules in the asymmetric unit [Bolognesi et al. (1975 ▸). Acta Cryst. A31, S119; Z′ = 2; no atomic coordinates available], wherea...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647395/ https://www.ncbi.nlm.nih.gov/pubmed/26594452 http://dx.doi.org/10.1107/S2056989015016151 |
Sumario: | The title compound, C(17)H(13)ClO, is the second monoclinic polymorph to crystallize in the space group P2(1)/c. The first polymorph crystallized with two independent molecules in the asymmetric unit [Bolognesi et al. (1975 ▸). Acta Cryst. A31, S119; Z′ = 2; no atomic coordinates available], whereas the title compound has Z′ = 1. In the title polymorph, the dihedral angle between the plane of the benzene ring of the tetralone moiety and that of the 4-chlorobenzyl ring is 52.21 (11)°. The cyclohex-2-en-1-one ring of the tetralone moiety has a screw-boat conformation. In the crystal, molecules are liked by pairs of C—H⋯π interactions forming inversion dimers. There are no other significant intermolecular interactions present. |
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