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Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide

In the title compound, C(26)H(37)NO, a new derivative of di­hydro­abietic acid, the two cyclo­hexene rings adopt half chair conformations, whereas the cyclo­hexane ring has a chair conformation. Each of the methyl groups is in an axial position with respect to the tricyclic hydro­phenanthrene residu...

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Detalles Bibliográficos
Autores principales: Liu, Li, Yan, Xin-Yan, Rao, Xiao-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647402/
https://www.ncbi.nlm.nih.gov/pubmed/26594487
http://dx.doi.org/10.1107/S2056989015017648
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author Liu, Li
Yan, Xin-Yan
Rao, Xiao-Ping
author_facet Liu, Li
Yan, Xin-Yan
Rao, Xiao-Ping
author_sort Liu, Li
collection PubMed
description In the title compound, C(26)H(37)NO, a new derivative of di­hydro­abietic acid, the two cyclo­hexene rings adopt half chair conformations, whereas the cyclo­hexane ring has a chair conformation. Each of the methyl groups is in an axial position with respect to the tricyclic hydro­phenanthrene residue. In the crystal packing, methyl­ene-C—H⋯π(phen­yl) inter­actions lead to supra­molecular helical chains along [010]; the amide-H atom does not form a significant inter­molecular inter­action owing to steric pressure.
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spelling pubmed-46474022015-11-20 Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide Liu, Li Yan, Xin-Yan Rao, Xiao-Ping Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(26)H(37)NO, a new derivative of di­hydro­abietic acid, the two cyclo­hexene rings adopt half chair conformations, whereas the cyclo­hexane ring has a chair conformation. Each of the methyl groups is in an axial position with respect to the tricyclic hydro­phenanthrene residue. In the crystal packing, methyl­ene-C—H⋯π(phen­yl) inter­actions lead to supra­molecular helical chains along [010]; the amide-H atom does not form a significant inter­molecular inter­action owing to steric pressure. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647402/ /pubmed/26594487 http://dx.doi.org/10.1107/S2056989015017648 Text en © Liu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Liu, Li
Yan, Xin-Yan
Rao, Xiao-Ping
Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
title Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
title_full Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
title_fullStr Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
title_full_unstemmed Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
title_short Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
title_sort crystal structure of 7-isopropyl-1,4a,n-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodeca­hydro­phenanthrene-1-carb­ox­amide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647402/
https://www.ncbi.nlm.nih.gov/pubmed/26594487
http://dx.doi.org/10.1107/S2056989015017648
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