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Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide
In the title compound, C(26)H(37)NO, a new derivative of dihydroabietic acid, the two cyclohexene rings adopt half chair conformations, whereas the cyclohexane ring has a chair conformation. Each of the methyl groups is in an axial position with respect to the tricyclic hydrophenanthrene residu...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647402/ https://www.ncbi.nlm.nih.gov/pubmed/26594487 http://dx.doi.org/10.1107/S2056989015017648 |
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author | Liu, Li Yan, Xin-Yan Rao, Xiao-Ping |
author_facet | Liu, Li Yan, Xin-Yan Rao, Xiao-Ping |
author_sort | Liu, Li |
collection | PubMed |
description | In the title compound, C(26)H(37)NO, a new derivative of dihydroabietic acid, the two cyclohexene rings adopt half chair conformations, whereas the cyclohexane ring has a chair conformation. Each of the methyl groups is in an axial position with respect to the tricyclic hydrophenanthrene residue. In the crystal packing, methylene-C—H⋯π(phenyl) interactions lead to supramolecular helical chains along [010]; the amide-H atom does not form a significant intermolecular interaction owing to steric pressure. |
format | Online Article Text |
id | pubmed-4647402 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46474022015-11-20 Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide Liu, Li Yan, Xin-Yan Rao, Xiao-Ping Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(26)H(37)NO, a new derivative of dihydroabietic acid, the two cyclohexene rings adopt half chair conformations, whereas the cyclohexane ring has a chair conformation. Each of the methyl groups is in an axial position with respect to the tricyclic hydrophenanthrene residue. In the crystal packing, methylene-C—H⋯π(phenyl) interactions lead to supramolecular helical chains along [010]; the amide-H atom does not form a significant intermolecular interaction owing to steric pressure. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647402/ /pubmed/26594487 http://dx.doi.org/10.1107/S2056989015017648 Text en © Liu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Liu, Li Yan, Xin-Yan Rao, Xiao-Ping Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
title | Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
title_full | Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
title_fullStr | Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
title_full_unstemmed | Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
title_short | Crystal structure of 7-isopropyl-1,4a,N-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
title_sort | crystal structure of 7-isopropyl-1,4a,n-trimethyl-1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1-carboxamide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647402/ https://www.ncbi.nlm.nih.gov/pubmed/26594487 http://dx.doi.org/10.1107/S2056989015017648 |
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