Crystal structure of (3S*,4S*,4aS*,5R*,6R*,6aS*,7R*,11aS*,11bR*)-5,6-bis(benzo­yloxy)-3,4a-dihy­droxy-4,7,11b-trimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodeca­hydro­phenanthro[3,2-b]furan-4-carb­oxy­lic acid methanol monosolvate

The title compound, C(34)H(36)O(9)·CH(3)OH, is a diterpenoid isolated from the roots of Caesalpinia pulcherrima (L.) Swartz. The three trans-fused six-membered rings are in chair, chair and half-chair conformations. The mean plane of this fused-ring system makes dihedral angles of 67.95 (15) and 83....

Descripción completa

Detalles Bibliográficos
Autores principales: Siddiqui, Sadaf, Erharuyi, Osayemwenre, Falodun, Abiodun, Choudhary, M. Iqbal, Yousuf, Sammer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647408/
https://www.ncbi.nlm.nih.gov/pubmed/26594451
http://dx.doi.org/10.1107/S2056989015016461
Descripción
Sumario:The title compound, C(34)H(36)O(9)·CH(3)OH, is a diterpenoid isolated from the roots of Caesalpinia pulcherrima (L.) Swartz. The three trans-fused six-membered rings are in chair, chair and half-chair conformations. The mean plane of this fused-ring system makes dihedral angles of 67.95 (15) and 83.72 (14)° with the two phenyl rings of the benzo­yloxy groups. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, forming an infinite chain along the b-axis direction.

Ejemplares similares