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Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate

In the title thio­phene derivative, C(13)H(18)N(2)O(3)S, the dihedral angles between the thio­phene ring and the [(di­methyl­amino)­methyl­idene]amino side chain (r.m.s. deviation = 0.009 Å) and the –CO(2) ester group are 3.01 (16) and 59.9 (3)°, respectively. In the crystal, inversion dimers linked...

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Autores principales: Prasad, N. L., Krishnamurthy, M. S., Nagarajaiah, H., Begum, Noor Shahina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647409/
https://www.ncbi.nlm.nih.gov/pubmed/26594465
http://dx.doi.org/10.1107/S2056989015016217
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author Prasad, N. L.
Krishnamurthy, M. S.
Nagarajaiah, H.
Begum, Noor Shahina
author_facet Prasad, N. L.
Krishnamurthy, M. S.
Nagarajaiah, H.
Begum, Noor Shahina
author_sort Prasad, N. L.
collection PubMed
description In the title thio­phene derivative, C(13)H(18)N(2)O(3)S, the dihedral angles between the thio­phene ring and the [(di­methyl­amino)­methyl­idene]amino side chain (r.m.s. deviation = 0.009 Å) and the –CO(2) ester group are 3.01 (16) and 59.9 (3)°, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(16) loops. The dimers are linked by another weak C—H⋯O inter­action, forming chains along [001]. In addition, weak C—H⋯π inter­actions are observed, which link the chains into (001) layers.
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spelling pubmed-46474092015-11-20 Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate Prasad, N. L. Krishnamurthy, M. S. Nagarajaiah, H. Begum, Noor Shahina Acta Crystallogr E Crystallogr Commun Data Reports In the title thio­phene derivative, C(13)H(18)N(2)O(3)S, the dihedral angles between the thio­phene ring and the [(di­methyl­amino)­methyl­idene]amino side chain (r.m.s. deviation = 0.009 Å) and the –CO(2) ester group are 3.01 (16) and 59.9 (3)°, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(16) loops. The dimers are linked by another weak C—H⋯O inter­action, forming chains along [001]. In addition, weak C—H⋯π inter­actions are observed, which link the chains into (001) layers. International Union of Crystallography 2015-09-17 /pmc/articles/PMC4647409/ /pubmed/26594465 http://dx.doi.org/10.1107/S2056989015016217 Text en © Prasad et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Prasad, N. L.
Krishnamurthy, M. S.
Nagarajaiah, H.
Begum, Noor Shahina
Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
title Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
title_full Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
title_fullStr Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
title_full_unstemmed Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
title_short Crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
title_sort crystal structure of ethyl 5-acetyl-2-{[(di­methyl­amino)­methyl­idene]amino}-4-methyl­thio­phene-3-carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647409/
https://www.ncbi.nlm.nih.gov/pubmed/26594465
http://dx.doi.org/10.1107/S2056989015016217
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