Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride

The title compound, [RuCl(C(10)H(14))(C(11)H(10)N(4))]Cl is an Ru(II) complex in which an η(6)-p-cymene ligand, two N atoms of 3-amino-2-(phenyl­azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an impor...

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Detalles Bibliográficos
Autores principales: Hansongnern, Kanidtha, Sansook, Supojjanee, Romin, Thassani, Nimthong Roldan, Arunpatcha, Pakawatchai, Chaveng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647410/
https://www.ncbi.nlm.nih.gov/pubmed/26594428
http://dx.doi.org/10.1107/S2056989015017466
Descripción
Sumario:The title compound, [RuCl(C(10)H(14))(C(11)H(10)N(4))]Cl is an Ru(II) complex in which an η(6)-p-cymene ligand, two N atoms of 3-amino-2-(phenyl­azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78 (5) and 0.22 (5).

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