Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride

The title compound, [RuCl(C(10)H(14))(C(11)H(10)N(4))]Cl is an Ru(II) complex in which an η(6)-p-cymene ligand, two N atoms of 3-amino-2-(phenyl­azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an impor...

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Autores principales: Hansongnern, Kanidtha, Sansook, Supojjanee, Romin, Thassani, Nimthong Roldan, Arunpatcha, Pakawatchai, Chaveng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647410/
https://www.ncbi.nlm.nih.gov/pubmed/26594428
http://dx.doi.org/10.1107/S2056989015017466
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author Hansongnern, Kanidtha
Sansook, Supojjanee
Romin, Thassani
Nimthong Roldan, Arunpatcha
Pakawatchai, Chaveng
author_facet Hansongnern, Kanidtha
Sansook, Supojjanee
Romin, Thassani
Nimthong Roldan, Arunpatcha
Pakawatchai, Chaveng
author_sort Hansongnern, Kanidtha
collection PubMed
description The title compound, [RuCl(C(10)H(14))(C(11)H(10)N(4))]Cl is an Ru(II) complex in which an η(6)-p-cymene ligand, two N atoms of 3-amino-2-(phenyl­azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78 (5) and 0.22 (5).
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spelling pubmed-46474102015-11-20 Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride Hansongnern, Kanidtha Sansook, Supojjanee Romin, Thassani Nimthong Roldan, Arunpatcha Pakawatchai, Chaveng Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [RuCl(C(10)H(14))(C(11)H(10)N(4))]Cl is an Ru(II) complex in which an η(6)-p-cymene ligand, two N atoms of 3-amino-2-(phenyl­azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78 (5) and 0.22 (5). International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647410/ /pubmed/26594428 http://dx.doi.org/10.1107/S2056989015017466 Text en © Hansongnern et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hansongnern, Kanidtha
Sansook, Supojjanee
Romin, Thassani
Nimthong Roldan, Arunpatcha
Pakawatchai, Chaveng
Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride
title Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride
title_full Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride
title_fullStr Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride
title_full_unstemmed Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride
title_short Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(II) chloride
title_sort crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η(6)-p-cymene)­ruthenium(ii) chloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647410/
https://www.ncbi.nlm.nih.gov/pubmed/26594428
http://dx.doi.org/10.1107/S2056989015017466
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