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Crystal structure of 1′-ethyl­spiro[chroman-4,4′-imidazolidine]-2′,5′-dione: a hydantoine derivative

The title compound, C(13)H(13)N(2)O(3), a hydantoin derivative, crystallized with two mol­ecules (A and B) in an asymmetric unit. In mol­ecule A, the imidazolidine ring is twisted about the C—N bond involving the spiro C atom, while in mol­ecule B this ring is flat (r.m.s. deviation = 0.010 Å). The...

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Detalles Bibliográficos
Autores principales: Benaka Prasad, S. B., Naveen, S., Madaiah, M., Lokanath, N. K., Warad, Ismail, Abdoh, Muneer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647411/
https://www.ncbi.nlm.nih.gov/pubmed/26594433
http://dx.doi.org/10.1107/S2056989015016175
Descripción
Sumario:The title compound, C(13)H(13)N(2)O(3), a hydantoin derivative, crystallized with two mol­ecules (A and B) in an asymmetric unit. In mol­ecule A, the imidazolidine ring is twisted about the C—N bond involving the spiro C atom, while in mol­ecule B this ring is flat (r.m.s. deviation = 0.010 Å). The pyran rings in both mol­ecules have distorted half-chair conformations. The mean plane of the imidazolidine ring is inclined to the aromatic ring of the chroman unit by 79.71 (11)° in mol­ecule A and 82.83 (12)° in mol­ecule B. In the crystal, pairs of N—H⋯O hydrogen bonds link the individual mol­ecules to form A–A and B–B inversion dimers. The dimers are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming sheets lying parallel to the bc plane, viz. (011). Within the sheets, the A and B mol­ecules are linked by C—H⋯π inter­actions.