Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide

The title compound, C(20)H(29)NSi(+)·Br(−), contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetra­hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocycl...

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Detalles Bibliográficos
Autores principales: Barth, Eva Rebecca, Golz, Christopher, Koller, Stephan G., Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647413/
https://www.ncbi.nlm.nih.gov/pubmed/26594462
http://dx.doi.org/10.1107/S2056989015016965
Descripción
Sumario:The title compound, C(20)H(29)NSi(+)·Br(−), contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetra­hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant inter­molecular inter­action to be the electrostatic attraction between the ammonium cation and the bromide anion.

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