Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide

The title compound, C(20)H(29)NSi(+)·Br(−), contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetra­hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocycl...

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Detalles Bibliográficos
Autores principales: Barth, Eva Rebecca, Golz, Christopher, Koller, Stephan G., Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647413/
https://www.ncbi.nlm.nih.gov/pubmed/26594462
http://dx.doi.org/10.1107/S2056989015016965
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author Barth, Eva Rebecca
Golz, Christopher
Koller, Stephan G.
Strohmann, Carsten
author_facet Barth, Eva Rebecca
Golz, Christopher
Koller, Stephan G.
Strohmann, Carsten
author_sort Barth, Eva Rebecca
collection PubMed
description The title compound, C(20)H(29)NSi(+)·Br(−), contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetra­hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant inter­molecular inter­action to be the electrostatic attraction between the ammonium cation and the bromide anion.
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spelling pubmed-46474132015-11-20 Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide Barth, Eva Rebecca Golz, Christopher Koller, Stephan G. Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(20)H(29)NSi(+)·Br(−), contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetra­hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant inter­molecular inter­action to be the electrostatic attraction between the ammonium cation and the bromide anion. International Union of Crystallography 2015-09-17 /pmc/articles/PMC4647413/ /pubmed/26594462 http://dx.doi.org/10.1107/S2056989015016965 Text en © Barth et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Barth, Eva Rebecca
Golz, Christopher
Koller, Stephan G.
Strohmann, Carsten
Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
title Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
title_full Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
title_fullStr Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
title_full_unstemmed Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
title_short Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
title_sort crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647413/
https://www.ncbi.nlm.nih.gov/pubmed/26594462
http://dx.doi.org/10.1107/S2056989015016965
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