Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline

The title compound, C(12)H(9)N(3)O(2), adopts an E conformation at the imine double bond. The pyridyl ring makes a dihedral angle of 47.78 (5)° with the benzene ring, indicating the mol­ecule is twisted. In the crystal, mol­ecules are π–π stacked into columns parallel to [100], with an inter­planar...

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Detalles Bibliográficos
Autores principales: Saphu, Watcharin, Chainok, Kittipong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647417/
https://www.ncbi.nlm.nih.gov/pubmed/26594463
http://dx.doi.org/10.1107/S2056989015016928
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author Saphu, Watcharin
Chainok, Kittipong
author_facet Saphu, Watcharin
Chainok, Kittipong
author_sort Saphu, Watcharin
collection PubMed
description The title compound, C(12)H(9)N(3)O(2), adopts an E conformation at the imine double bond. The pyridyl ring makes a dihedral angle of 47.78 (5)° with the benzene ring, indicating the mol­ecule is twisted. In the crystal, mol­ecules are π–π stacked into columns parallel to [100], with an inter­planar separation of 3.8537 (8) Å, corresponding to the length of the a axis. The chains are further linked via weak C—H⋯O and C—H⋯N hydrogen bonds, forming two-dimensional sheets parallel to (010). The sheets interact by van der Waals inter­actions.
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spelling pubmed-46474172015-11-20 Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline Saphu, Watcharin Chainok, Kittipong Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(12)H(9)N(3)O(2), adopts an E conformation at the imine double bond. The pyridyl ring makes a dihedral angle of 47.78 (5)° with the benzene ring, indicating the mol­ecule is twisted. In the crystal, mol­ecules are π–π stacked into columns parallel to [100], with an inter­planar separation of 3.8537 (8) Å, corresponding to the length of the a axis. The chains are further linked via weak C—H⋯O and C—H⋯N hydrogen bonds, forming two-dimensional sheets parallel to (010). The sheets interact by van der Waals inter­actions. International Union of Crystallography 2015-09-17 /pmc/articles/PMC4647417/ /pubmed/26594463 http://dx.doi.org/10.1107/S2056989015016928 Text en © Saphu and Chainok 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Saphu, Watcharin
Chainok, Kittipong
Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline
title Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline
title_full Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline
title_fullStr Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline
title_full_unstemmed Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline
title_short Crystal structure of 4-nitro-N-[(pyridin-2-yl)methyl­idene]aniline
title_sort crystal structure of 4-nitro-n-[(pyridin-2-yl)methyl­idene]aniline
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647417/
https://www.ncbi.nlm.nih.gov/pubmed/26594463
http://dx.doi.org/10.1107/S2056989015016928
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