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Crystal structure of borated N,N,N′,N′-tetramethyldiaminomethane
In the title compound, {[(dimethylamino)methyl]dimethylamine}trihydridoboron, C(5)H(17)BN(2), the tetrahedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and m...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647418/ https://www.ncbi.nlm.nih.gov/pubmed/26594453 http://dx.doi.org/10.1107/S2056989015016813 |
Sumario: | In the title compound, {[(dimethylamino)methyl]dimethylamine}trihydridoboron, C(5)H(17)BN(2), the tetrahedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and methyl groups are slighly elongated to 1.481 (2) and 1.482 (2) Å at the borated N atom, whereas the distances between the other N atom and its methyl groups are only 1.461 (2) and 1.462 (2) Å. The studied crystal was twinned. The twin data refinement was subsequently carried out with a scale factor of 0.263 (1). The two lattices of the twin domains were rotated by 179.84°. |
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