Cargando…

Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane

In the title compound, {[(di­methyl­amino)­meth­yl]di­methyl­amine}­trihydridoboron, C(5)H(17)BN(2), the tetra­hedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and m...

Descripción completa

Detalles Bibliográficos
Autores principales: Louven, Kathrin, Quentin, Georgina, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647418/
https://www.ncbi.nlm.nih.gov/pubmed/26594453
http://dx.doi.org/10.1107/S2056989015016813
Descripción
Sumario:In the title compound, {[(di­methyl­amino)­meth­yl]di­methyl­amine}­trihydridoboron, C(5)H(17)BN(2), the tetra­hedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and methyl groups are slighly elongated to 1.481 (2) and 1.482 (2) Å at the borated N atom, whereas the distances between the other N atom and its methyl groups are only 1.461 (2) and 1.462 (2) Å. The studied crystal was twinned. The twin data refinement was subsequently carried out with a scale factor of 0.263 (1). The two lattices of the twin domains were rotated by 179.84°.