Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane

In the title compound, {[(di­methyl­amino)­meth­yl]di­methyl­amine}­trihydridoboron, C(5)H(17)BN(2), the tetra­hedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and m...

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Autores principales: Louven, Kathrin, Quentin, Georgina, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647418/
https://www.ncbi.nlm.nih.gov/pubmed/26594453
http://dx.doi.org/10.1107/S2056989015016813
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author Louven, Kathrin
Quentin, Georgina
Strohmann, Carsten
author_facet Louven, Kathrin
Quentin, Georgina
Strohmann, Carsten
author_sort Louven, Kathrin
collection PubMed
description In the title compound, {[(di­methyl­amino)­meth­yl]di­methyl­amine}­trihydridoboron, C(5)H(17)BN(2), the tetra­hedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and methyl groups are slighly elongated to 1.481 (2) and 1.482 (2) Å at the borated N atom, whereas the distances between the other N atom and its methyl groups are only 1.461 (2) and 1.462 (2) Å. The studied crystal was twinned. The twin data refinement was subsequently carried out with a scale factor of 0.263 (1). The two lattices of the twin domains were rotated by 179.84°.
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spelling pubmed-46474182015-11-20 Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane Louven, Kathrin Quentin, Georgina Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, {[(di­methyl­amino)­meth­yl]di­methyl­amine}­trihydridoboron, C(5)H(17)BN(2), the tetra­hedral geometry of the N—C—N unit is slightly disorted. As a result of the bulky amine substituents, a wider N—C—N angle of 113.6 (1)° is observed. The bond lengths between the N atom and methyl groups are slighly elongated to 1.481 (2) and 1.482 (2) Å at the borated N atom, whereas the distances between the other N atom and its methyl groups are only 1.461 (2) and 1.462 (2) Å. The studied crystal was twinned. The twin data refinement was subsequently carried out with a scale factor of 0.263 (1). The two lattices of the twin domains were rotated by 179.84°. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647418/ /pubmed/26594453 http://dx.doi.org/10.1107/S2056989015016813 Text en © Louven et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Louven, Kathrin
Quentin, Georgina
Strohmann, Carsten
Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane
title Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane
title_full Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane
title_fullStr Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane
title_full_unstemmed Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane
title_short Crystal structure of borated N,N,N′,N′-tetra­methyldi­amino­methane
title_sort crystal structure of borated n,n,n′,n′-tetra­methyldi­amino­methane
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647418/
https://www.ncbi.nlm.nih.gov/pubmed/26594453
http://dx.doi.org/10.1107/S2056989015016813
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