Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate

The asymmetric unit of the title salt, C(7)H(7)N(2) (+)·BF(4) (−), comprises two independent but nearly identical formula units. The solid-state structure comprises corrugated layers of cations and anions, formed by C—H⋯F hydrogen bonding, that are approximately parallel to (010). Further C—H⋯F hydr...

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Autores principales: Vaccaro, Francesca A., Koplitz, Lynn V., Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647419/
https://www.ncbi.nlm.nih.gov/pubmed/26594429
http://dx.doi.org/10.1107/S2056989015016011
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author Vaccaro, Francesca A.
Koplitz, Lynn V.
Mague, Joel T.
author_facet Vaccaro, Francesca A.
Koplitz, Lynn V.
Mague, Joel T.
author_sort Vaccaro, Francesca A.
collection PubMed
description The asymmetric unit of the title salt, C(7)H(7)N(2) (+)·BF(4) (−), comprises two independent but nearly identical formula units. The solid-state structure comprises corrugated layers of cations and anions, formed by C—H⋯F hydrogen bonding, that are approximately parallel to (010). Further C—H⋯F hydrogen bonding consolidates the three-dimensional architecture. The sample was refined as a two-component non-merohedral twin.
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spelling pubmed-46474192015-11-20 Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate Vaccaro, Francesca A. Koplitz, Lynn V. Mague, Joel T. Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title salt, C(7)H(7)N(2) (+)·BF(4) (−), comprises two independent but nearly identical formula units. The solid-state structure comprises corrugated layers of cations and anions, formed by C—H⋯F hydrogen bonding, that are approximately parallel to (010). Further C—H⋯F hydrogen bonding consolidates the three-dimensional architecture. The sample was refined as a two-component non-merohedral twin. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647419/ /pubmed/26594429 http://dx.doi.org/10.1107/S2056989015016011 Text en © Vaccaro et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Vaccaro, Francesca A.
Koplitz, Lynn V.
Mague, Joel T.
Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
title Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
title_full Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
title_fullStr Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
title_full_unstemmed Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
title_short Crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
title_sort crystal structure of 2-cyano-1-methyl­pyridinium tetra­fluoro­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647419/
https://www.ncbi.nlm.nih.gov/pubmed/26594429
http://dx.doi.org/10.1107/S2056989015016011
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