Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide

In the title compound, C(5)H(2)Cl(2)N(2)O(3), the nitro group is essentially coplanar with the aromatic ring, with a twist angle of 4.00 (6)° and a fold angle of 2.28 (17)°. The crystal structure exhibits a herringbone pattern with the zigzag running along the b axis. The herringbone layer-to-layer...

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Autores principales: Prichard, Andrew M., Lynch, Will E., Padgett, Clifford W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647420/
https://www.ncbi.nlm.nih.gov/pubmed/26594473
http://dx.doi.org/10.1107/S2056989015017387
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author Prichard, Andrew M.
Lynch, Will E.
Padgett, Clifford W.
author_facet Prichard, Andrew M.
Lynch, Will E.
Padgett, Clifford W.
author_sort Prichard, Andrew M.
collection PubMed
description In the title compound, C(5)H(2)Cl(2)N(2)O(3), the nitro group is essentially coplanar with the aromatic ring, with a twist angle of 4.00 (6)° and a fold angle of 2.28 (17)°. The crystal structure exhibits a herringbone pattern with the zigzag running along the b axis. The herringbone layer-to-layer distance is 3.0075 (15) Å, with a shift of 5.150 (4) Å. Neighboring mol­ecules are tilted at a 57.83 (4)° (ring-to-ring) angle with each other. The nitro group on one mol­ecule points to the N-oxide group on the neighboring one, with an inter­molecular O⋯N(nitro) distance of 3.1725 (13) Å.
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spelling pubmed-46474202015-11-20 Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide Prichard, Andrew M. Lynch, Will E. Padgett, Clifford W. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(5)H(2)Cl(2)N(2)O(3), the nitro group is essentially coplanar with the aromatic ring, with a twist angle of 4.00 (6)° and a fold angle of 2.28 (17)°. The crystal structure exhibits a herringbone pattern with the zigzag running along the b axis. The herringbone layer-to-layer distance is 3.0075 (15) Å, with a shift of 5.150 (4) Å. Neighboring mol­ecules are tilted at a 57.83 (4)° (ring-to-ring) angle with each other. The nitro group on one mol­ecule points to the N-oxide group on the neighboring one, with an inter­molecular O⋯N(nitro) distance of 3.1725 (13) Å. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647420/ /pubmed/26594473 http://dx.doi.org/10.1107/S2056989015017387 Text en © Prichard et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Prichard, Andrew M.
Lynch, Will E.
Padgett, Clifford W.
Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide
title Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide
title_full Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide
title_fullStr Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide
title_full_unstemmed Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide
title_short Crystal structure of 2,6-di­chloro-4-nitro­pyridine N-oxide
title_sort crystal structure of 2,6-di­chloro-4-nitro­pyridine n-oxide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647420/
https://www.ncbi.nlm.nih.gov/pubmed/26594473
http://dx.doi.org/10.1107/S2056989015017387
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