Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]

The title compound, [Re(2)(C(3)H(7)COO)(2)Cl(4){(CH(3))(2)SO}(2)], comprises binuclear complex mol­ecules [Re—Re = 2.24502 (13) Å] involving cis-oriented double carboxyl­ate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at...

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Detalles Bibliográficos
Autores principales: Golichenko, Alexander A., Shtemenko, Alexander V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647422/
https://www.ncbi.nlm.nih.gov/pubmed/26594411
http://dx.doi.org/10.1107/S2056989015017429
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author Golichenko, Alexander A.
Shtemenko, Alexander V.
author_facet Golichenko, Alexander A.
Shtemenko, Alexander V.
author_sort Golichenko, Alexander A.
collection PubMed
description The title compound, [Re(2)(C(3)H(7)COO)(2)Cl(4){(CH(3))(2)SO}(2)], comprises binuclear complex mol­ecules [Re—Re = 2.24502 (13) Å] involving cis-oriented double carboxyl­ate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the Re(III) atoms. In the crystal, mol­ecules are linked into corrugated layers parallel to (101) by very weak C—H⋯Cl and C—H⋯O hydrogen-bonding inter­actions. C—H⋯Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework.
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spelling pubmed-46474222015-11-20 Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)] Golichenko, Alexander A. Shtemenko, Alexander V. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Re(2)(C(3)H(7)COO)(2)Cl(4){(CH(3))(2)SO}(2)], comprises binuclear complex mol­ecules [Re—Re = 2.24502 (13) Å] involving cis-oriented double carboxyl­ate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the Re(III) atoms. In the crystal, mol­ecules are linked into corrugated layers parallel to (101) by very weak C—H⋯Cl and C—H⋯O hydrogen-bonding inter­actions. C—H⋯Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647422/ /pubmed/26594411 http://dx.doi.org/10.1107/S2056989015017429 Text en © Golichenko and Shtemenko 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Golichenko, Alexander A.
Shtemenko, Alexander V.
Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]
title Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]
title_full Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]
title_fullStr Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]
title_full_unstemmed Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]
title_short Crystal structure of di-μ-isobutyrato-κ(4) O:O′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κS)rhenium(III)]
title_sort crystal structure of di-μ-isobutyrato-κ(4) o:o′-bis­[cis-di­chlorido­(dimethyl sulfoxide-κs)rhenium(iii)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647422/
https://www.ncbi.nlm.nih.gov/pubmed/26594411
http://dx.doi.org/10.1107/S2056989015017429
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