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Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose

The title compound, C(21)H(29)NO(7) (1) [systematic name: benzyl ({(3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-di­methyl­tetrahydro­furo[2,3-d][1,3]dioxol-6-yl}meth­yl)carbamate], consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose rin...

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Autores principales: Rjabovs, Vitalijs, Stepanovs, Dmitrijs, Turks, Maris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647424/
https://www.ncbi.nlm.nih.gov/pubmed/26594409
http://dx.doi.org/10.1107/S2056989015017582
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author Rjabovs, Vitalijs
Stepanovs, Dmitrijs
Turks, Maris
author_facet Rjabovs, Vitalijs
Stepanovs, Dmitrijs
Turks, Maris
author_sort Rjabovs, Vitalijs
collection PubMed
description The title compound, C(21)H(29)NO(7) (1) [systematic name: benzyl ({(3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-di­methyl­tetrahydro­furo[2,3-d][1,3]dioxol-6-yl}meth­yl)carbamate], consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring adopts an envelope conformation close to C (3)-exo, where the C atom substituted by the benzyl carbamate group is the flap. The fused dioxolane ring also adopts an envelope conformation, as does the terminal dioxolane ring, with in each case an O atom as the flap. In the crystal, mol­ecules are linked by N—H⋯O and C–H⋯O hydrogen bonds, forming chains propagating along the b-axis direction.
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spelling pubmed-46474242015-11-20 Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose Rjabovs, Vitalijs Stepanovs, Dmitrijs Turks, Maris Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(21)H(29)NO(7) (1) [systematic name: benzyl ({(3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-di­methyl­tetrahydro­furo[2,3-d][1,3]dioxol-6-yl}meth­yl)carbamate], consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring adopts an envelope conformation close to C (3)-exo, where the C atom substituted by the benzyl carbamate group is the flap. The fused dioxolane ring also adopts an envelope conformation, as does the terminal dioxolane ring, with in each case an O atom as the flap. In the crystal, mol­ecules are linked by N—H⋯O and C–H⋯O hydrogen bonds, forming chains propagating along the b-axis direction. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647424/ /pubmed/26594409 http://dx.doi.org/10.1107/S2056989015017582 Text en © Rjabovs et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rjabovs, Vitalijs
Stepanovs, Dmitrijs
Turks, Maris
Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_full Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_fullStr Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_full_unstemmed Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_short Crystal structure of 3-C-(N-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_sort crystal structure of 3-c-(n-benzyl­oxy­carbon­yl)amino­methyl-3-de­oxy-1,2:5,6-di-o-iso­propyl­idene-α-d-allo­furan­ose
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647424/
https://www.ncbi.nlm.nih.gov/pubmed/26594409
http://dx.doi.org/10.1107/S2056989015017582
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