Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)

The title cyclo­metalated platinum(II) complex with 2-(4-bromo­phen­yl)pyridinato and acetyl­acetonato ligands, [Pt(C(11)H(7)BrN)(C(5)H(7)O(2))], consists of two crystallographically non-equivalent dimers, each stacked by π–π inter­actions with distances of ≃ 3.4 Å. In both dimers, the platinum(II)...

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Detalles Bibliográficos
Autores principales: Fukuda, Keito, Sugaya, Tomoaki, Ishihara, Koji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647431/
https://www.ncbi.nlm.nih.gov/pubmed/26594420
http://dx.doi.org/10.1107/S2056989015017478
Descripción
Sumario:The title cyclo­metalated platinum(II) complex with 2-(4-bromo­phen­yl)pyridinato and acetyl­acetonato ligands, [Pt(C(11)H(7)BrN)(C(5)H(7)O(2))], consists of two crystallographically non-equivalent dimers, each stacked by π–π inter­actions with distances of ≃ 3.4 Å. In both dimers, the platinum(II) complexes are arranged anti­parallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the Pt(II) atom in these complexes are 0.08 (12) and 1.54 (9)°.

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