Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)

The title cyclo­metalated platinum(II) complex with 2-(4-bromo­phen­yl)pyridinato and acetyl­acetonato ligands, [Pt(C(11)H(7)BrN)(C(5)H(7)O(2))], consists of two crystallographically non-equivalent dimers, each stacked by π–π inter­actions with distances of ≃ 3.4 Å. In both dimers, the platinum(II)...

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Detalles Bibliográficos
Autores principales: Fukuda, Keito, Sugaya, Tomoaki, Ishihara, Koji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647431/
https://www.ncbi.nlm.nih.gov/pubmed/26594420
http://dx.doi.org/10.1107/S2056989015017478
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author Fukuda, Keito
Sugaya, Tomoaki
Ishihara, Koji
author_facet Fukuda, Keito
Sugaya, Tomoaki
Ishihara, Koji
author_sort Fukuda, Keito
collection PubMed
description The title cyclo­metalated platinum(II) complex with 2-(4-bromo­phen­yl)pyridinato and acetyl­acetonato ligands, [Pt(C(11)H(7)BrN)(C(5)H(7)O(2))], consists of two crystallographically non-equivalent dimers, each stacked by π–π inter­actions with distances of ≃ 3.4 Å. In both dimers, the platinum(II) complexes are arranged anti­parallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the Pt(II) atom in these complexes are 0.08 (12) and 1.54 (9)°.
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spelling pubmed-46474312015-11-20 Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II) Fukuda, Keito Sugaya, Tomoaki Ishihara, Koji Acta Crystallogr E Crystallogr Commun Research Communications The title cyclo­metalated platinum(II) complex with 2-(4-bromo­phen­yl)pyridinato and acetyl­acetonato ligands, [Pt(C(11)H(7)BrN)(C(5)H(7)O(2))], consists of two crystallographically non-equivalent dimers, each stacked by π–π inter­actions with distances of ≃ 3.4 Å. In both dimers, the platinum(II) complexes are arranged anti­parallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the Pt(II) atom in these complexes are 0.08 (12) and 1.54 (9)°. International Union of Crystallography 2015-09-30 /pmc/articles/PMC4647431/ /pubmed/26594420 http://dx.doi.org/10.1107/S2056989015017478 Text en © Fukuda et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Fukuda, Keito
Sugaya, Tomoaki
Ishihara, Koji
Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)
title Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)
title_full Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)
title_fullStr Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)
title_full_unstemmed Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)
title_short Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O′)platinum(II)
title_sort crystal structure of [5-bromo-2-(pyridin-2-yl-κn)phenyl-κc (1)](pentane-2,4-dionato-κ (2) o,o′)platinum(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647431/
https://www.ncbi.nlm.nih.gov/pubmed/26594420
http://dx.doi.org/10.1107/S2056989015017478
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