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Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol
In the title compound, C(9)H(16)O(4), the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å. The spiro-fused cyclohexane ring shows a chair form. The hydroxy group substituted in an ax...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647432/ https://www.ncbi.nlm.nih.gov/pubmed/26594401 http://dx.doi.org/10.1107/S2056989015016783 |
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author | Oishi, Takeshi Yamamoto, Hiroaki Sugai, Tomoya Fukaya, Keisuke Yamaguchi, Yu Watanabe, Ami Sato, Takaaki Chida, Noritaka |
author_facet | Oishi, Takeshi Yamamoto, Hiroaki Sugai, Tomoya Fukaya, Keisuke Yamaguchi, Yu Watanabe, Ami Sato, Takaaki Chida, Noritaka |
author_sort | Oishi, Takeshi |
collection | PubMed |
description | In the title compound, C(9)H(16)O(4), the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å. The spiro-fused cyclohexane ring shows a chair form. The hydroxy group substituted in an axial position makes an intramolecular O—H⋯O hydrogen bond with one of the O atoms in the cyclic ether, forming an S(6) ring motif. In the crystal, the O—H⋯O hydrogen bond involving the equatorial hydroxy group connects the molecules into a zigzag chain with a C(5) motif running along the c axis. |
format | Online Article Text |
id | pubmed-4647432 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46474322015-11-20 Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol Oishi, Takeshi Yamamoto, Hiroaki Sugai, Tomoya Fukaya, Keisuke Yamaguchi, Yu Watanabe, Ami Sato, Takaaki Chida, Noritaka Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(9)H(16)O(4), the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å. The spiro-fused cyclohexane ring shows a chair form. The hydroxy group substituted in an axial position makes an intramolecular O—H⋯O hydrogen bond with one of the O atoms in the cyclic ether, forming an S(6) ring motif. In the crystal, the O—H⋯O hydrogen bond involving the equatorial hydroxy group connects the molecules into a zigzag chain with a C(5) motif running along the c axis. International Union of Crystallography 2015-09-17 /pmc/articles/PMC4647432/ /pubmed/26594401 http://dx.doi.org/10.1107/S2056989015016783 Text en © Oishi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Oishi, Takeshi Yamamoto, Hiroaki Sugai, Tomoya Fukaya, Keisuke Yamaguchi, Yu Watanabe, Ami Sato, Takaaki Chida, Noritaka Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
title | Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
title_full | Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
title_fullStr | Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
title_full_unstemmed | Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
title_short | Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
title_sort | crystal structure of (±)-(7rs,8sr)-7-methyl-1,4-dioxaspiro[4.5]decane-7,8-diol |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647432/ https://www.ncbi.nlm.nih.gov/pubmed/26594401 http://dx.doi.org/10.1107/S2056989015016783 |
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