Cargando…

Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol

In the title compound, C(9)H(16)O(4), the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å. The spiro-fused cyclo­hexane ring shows a chair form. The hy­droxy group substituted in an ax...

Descripción completa

Detalles Bibliográficos
Autores principales: Oishi, Takeshi, Yamamoto, Hiroaki, Sugai, Tomoya, Fukaya, Keisuke, Yamaguchi, Yu, Watanabe, Ami, Sato, Takaaki, Chida, Noritaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647432/
https://www.ncbi.nlm.nih.gov/pubmed/26594401
http://dx.doi.org/10.1107/S2056989015016783
_version_ 1782401097744252928
author Oishi, Takeshi
Yamamoto, Hiroaki
Sugai, Tomoya
Fukaya, Keisuke
Yamaguchi, Yu
Watanabe, Ami
Sato, Takaaki
Chida, Noritaka
author_facet Oishi, Takeshi
Yamamoto, Hiroaki
Sugai, Tomoya
Fukaya, Keisuke
Yamaguchi, Yu
Watanabe, Ami
Sato, Takaaki
Chida, Noritaka
author_sort Oishi, Takeshi
collection PubMed
description In the title compound, C(9)H(16)O(4), the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å. The spiro-fused cyclo­hexane ring shows a chair form. The hy­droxy group substituted in an axial position makes an intra­molecular O—H⋯O hydrogen bond with one of the O atoms in the cyclic ether, forming an S(6) ring motif. In the crystal, the O—H⋯O hydrogen bond involving the equatorial hy­droxy group connects the mol­ecules into a zigzag chain with a C(5) motif running along the c axis.
format Online
Article
Text
id pubmed-4647432
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-46474322015-11-20 Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol Oishi, Takeshi Yamamoto, Hiroaki Sugai, Tomoya Fukaya, Keisuke Yamaguchi, Yu Watanabe, Ami Sato, Takaaki Chida, Noritaka Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(9)H(16)O(4), the five-membered dioxolane ring adopts a twist conformation; two adjacent C atoms deviate alternately from the mean plane of other atoms by −0.297 (4) and 0.288 (4) Å. The spiro-fused cyclo­hexane ring shows a chair form. The hy­droxy group substituted in an axial position makes an intra­molecular O—H⋯O hydrogen bond with one of the O atoms in the cyclic ether, forming an S(6) ring motif. In the crystal, the O—H⋯O hydrogen bond involving the equatorial hy­droxy group connects the mol­ecules into a zigzag chain with a C(5) motif running along the c axis. International Union of Crystallography 2015-09-17 /pmc/articles/PMC4647432/ /pubmed/26594401 http://dx.doi.org/10.1107/S2056989015016783 Text en © Oishi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Oishi, Takeshi
Yamamoto, Hiroaki
Sugai, Tomoya
Fukaya, Keisuke
Yamaguchi, Yu
Watanabe, Ami
Sato, Takaaki
Chida, Noritaka
Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
title Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
title_full Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
title_fullStr Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
title_full_unstemmed Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
title_short Crystal structure of (±)-(7RS,8SR)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
title_sort crystal structure of (±)-(7rs,8sr)-7-methyl-1,4-dioxa­spiro­[4.5]decane-7,8-diol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647432/
https://www.ncbi.nlm.nih.gov/pubmed/26594401
http://dx.doi.org/10.1107/S2056989015016783
work_keys_str_mv AT oishitakeshi crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT yamamotohiroaki crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT sugaitomoya crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT fukayakeisuke crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT yamaguchiyu crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT watanabeami crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT satotakaaki crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol
AT chidanoritaka crystalstructureof7rs8sr7methyl14dioxaspiro45decane78diol