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Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate)
In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the indole ring systems (r.m.s. deviations = 0.0263 and 0.0160 Å) are approximately perpendicular to one another, making a dihedral angle of 84.0 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647434/ https://www.ncbi.nlm.nih.gov/pubmed/26594391 http://dx.doi.org/10.1107/S205698901501628X |
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author | Sun, Hong-Shun Li, Yu-long Jiang, Hong Xu, Ning Xu, Hong |
author_facet | Sun, Hong-Shun Li, Yu-long Jiang, Hong Xu, Ning Xu, Hong |
author_sort | Sun, Hong-Shun |
collection | PubMed |
description | In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the indole ring systems (r.m.s. deviations = 0.0263 and 0.0160 Å) are approximately perpendicular to one another, making a dihedral angle of 84.0 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 89.5 (5) and 84.6 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagated along the b-axis direction. Weak C—H⋯π interactions are observed between neighbouring chains. |
format | Online Article Text |
id | pubmed-4647434 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46474342015-11-20 Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) Sun, Hong-Shun Li, Yu-long Jiang, Hong Xu, Ning Xu, Hong Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the indole ring systems (r.m.s. deviations = 0.0263 and 0.0160 Å) are approximately perpendicular to one another, making a dihedral angle of 84.0 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 89.5 (5) and 84.6 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagated along the b-axis direction. Weak C—H⋯π interactions are observed between neighbouring chains. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647434/ /pubmed/26594391 http://dx.doi.org/10.1107/S205698901501628X Text en © Sun et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Sun, Hong-Shun Li, Yu-long Jiang, Hong Xu, Ning Xu, Hong Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title | Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_full | Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_fullStr | Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_full_unstemmed | Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_short | Crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_sort | crystal structure of dimethyl 3,3′-[(4-fluorophenyl)methylene]bis(1h-indole-2-carboxylate) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647434/ https://www.ncbi.nlm.nih.gov/pubmed/26594391 http://dx.doi.org/10.1107/S205698901501628X |
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