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Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)

In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the indole ring systems (r.m.s. deviations = 0.0263 and 0.0160 Å) are approximately perpendic­ular to one another, making a dihedral angle of 84.0 (5)°; the fluoro­benzene ring is twisted with respect to the mean planes of the two indole...

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Detalles Bibliográficos
Autores principales: Sun, Hong-Shun, Li, Yu-long, Jiang, Hong, Xu, Ning, Xu, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647434/
https://www.ncbi.nlm.nih.gov/pubmed/26594391
http://dx.doi.org/10.1107/S205698901501628X
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author Sun, Hong-Shun
Li, Yu-long
Jiang, Hong
Xu, Ning
Xu, Hong
author_facet Sun, Hong-Shun
Li, Yu-long
Jiang, Hong
Xu, Ning
Xu, Hong
author_sort Sun, Hong-Shun
collection PubMed
description In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the indole ring systems (r.m.s. deviations = 0.0263 and 0.0160 Å) are approximately perpendic­ular to one another, making a dihedral angle of 84.0 (5)°; the fluoro­benzene ring is twisted with respect to the mean planes of the two indole ring systems at 89.5 (5) and 84.6 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supra­molecular chains propagated along the b-axis direction. Weak C—H⋯π inter­actions are observed between neighbouring chains.
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spelling pubmed-46474342015-11-20 Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) Sun, Hong-Shun Li, Yu-long Jiang, Hong Xu, Ning Xu, Hong Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the indole ring systems (r.m.s. deviations = 0.0263 and 0.0160 Å) are approximately perpendic­ular to one another, making a dihedral angle of 84.0 (5)°; the fluoro­benzene ring is twisted with respect to the mean planes of the two indole ring systems at 89.5 (5) and 84.6 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supra­molecular chains propagated along the b-axis direction. Weak C—H⋯π inter­actions are observed between neighbouring chains. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647434/ /pubmed/26594391 http://dx.doi.org/10.1107/S205698901501628X Text en © Sun et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sun, Hong-Shun
Li, Yu-long
Jiang, Hong
Xu, Ning
Xu, Hong
Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_full Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_fullStr Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_full_unstemmed Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_short Crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_sort crystal structure of dimethyl 3,3′-[(4-fluoro­phen­yl)methyl­ene]bis­(1h-indole-2-carboxyl­ate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647434/
https://www.ncbi.nlm.nih.gov/pubmed/26594391
http://dx.doi.org/10.1107/S205698901501628X
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