Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate

The reaction of pyrrole-2-carboxaldehyde and 2-(methyl­sulfan­yl)aniline in refluxing methanol gave an olive-green residue in which yellow crystals of the title compound, C(12)H(12)N(2)S·CH(3)OH, were grown from slow evaporation of methanol at 263 K. In the crystal, hydrogen-bonding inter­actions li...

Descripción completa

Detalles Bibliográficos
Autores principales: Richards, D. Douglas, Ang, M. Trisha C., McDonald, Robert, Bierenstiel, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647435/
https://www.ncbi.nlm.nih.gov/pubmed/26594390
http://dx.doi.org/10.1107/S205698901501590X
Descripción
Sumario:The reaction of pyrrole-2-carboxaldehyde and 2-(methyl­sulfan­yl)aniline in refluxing methanol gave an olive-green residue in which yellow crystals of the title compound, C(12)H(12)N(2)S·CH(3)OH, were grown from slow evaporation of methanol at 263 K. In the crystal, hydrogen-bonding inter­actions link the aniline mol­ecule and a nearby methanol solvent mol­ecule. These units are linked by a pair of weak C—H⋯O(methanol) interactions, forming inversion dimers consisting of two main molecules and two solvent molecules.

Ejemplares similares