Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate

The reaction of pyrrole-2-carboxaldehyde and 2-(methyl­sulfan­yl)aniline in refluxing methanol gave an olive-green residue in which yellow crystals of the title compound, C(12)H(12)N(2)S·CH(3)OH, were grown from slow evaporation of methanol at 263 K. In the crystal, hydrogen-bonding inter­actions li...

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Autores principales: Richards, D. Douglas, Ang, M. Trisha C., McDonald, Robert, Bierenstiel, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647435/
https://www.ncbi.nlm.nih.gov/pubmed/26594390
http://dx.doi.org/10.1107/S205698901501590X
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author Richards, D. Douglas
Ang, M. Trisha C.
McDonald, Robert
Bierenstiel, Matthias
author_facet Richards, D. Douglas
Ang, M. Trisha C.
McDonald, Robert
Bierenstiel, Matthias
author_sort Richards, D. Douglas
collection PubMed
description The reaction of pyrrole-2-carboxaldehyde and 2-(methyl­sulfan­yl)aniline in refluxing methanol gave an olive-green residue in which yellow crystals of the title compound, C(12)H(12)N(2)S·CH(3)OH, were grown from slow evaporation of methanol at 263 K. In the crystal, hydrogen-bonding inter­actions link the aniline mol­ecule and a nearby methanol solvent mol­ecule. These units are linked by a pair of weak C—H⋯O(methanol) interactions, forming inversion dimers consisting of two main molecules and two solvent molecules.
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spelling pubmed-46474352015-11-20 Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate Richards, D. Douglas Ang, M. Trisha C. McDonald, Robert Bierenstiel, Matthias Acta Crystallogr E Crystallogr Commun Research Communications The reaction of pyrrole-2-carboxaldehyde and 2-(methyl­sulfan­yl)aniline in refluxing methanol gave an olive-green residue in which yellow crystals of the title compound, C(12)H(12)N(2)S·CH(3)OH, were grown from slow evaporation of methanol at 263 K. In the crystal, hydrogen-bonding inter­actions link the aniline mol­ecule and a nearby methanol solvent mol­ecule. These units are linked by a pair of weak C—H⋯O(methanol) interactions, forming inversion dimers consisting of two main molecules and two solvent molecules. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647435/ /pubmed/26594390 http://dx.doi.org/10.1107/S205698901501590X Text en © Richards et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Richards, D. Douglas
Ang, M. Trisha C.
McDonald, Robert
Bierenstiel, Matthias
Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
title Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
title_full Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
title_fullStr Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
title_full_unstemmed Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
title_short Structure and spectroscopic properties of N,S-coordinating 2-methyl­sulfanyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
title_sort structure and spectroscopic properties of n,s-coordinating 2-methyl­sulfanyl-n-[(1h-pyrrol-2-yl)methyl­idene]aniline methanol monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647435/
https://www.ncbi.nlm.nih.gov/pubmed/26594390
http://dx.doi.org/10.1107/S205698901501590X
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