Crystal structure of 4-[(E)-(2-carbamo­thio­ylhydrazinyl­idene)meth­yl]benzoic acid

The title compound, C(9)H(9)N(3)O(2)S, is close to planar with an r.m.s. deviation of 0.032 Å. An intra­molecular N—H⋯N hydrogen bond closes an S(5) ring. In the crystal, mol­ecules are connected into inversion dimers of the R (2) (2)(8) type by pairs of O—H⋯O inter­actions. The dimers are further c...

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Detalles Bibliográficos
Autores principales: Tahir, Muhammad Nawaz, Anwar-ul-Haq, Muhammad, Choudhary, Muhammad Aziz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647436/
https://www.ncbi.nlm.nih.gov/pubmed/26594471
http://dx.doi.org/10.1107/S2056989015017594
Descripción
Sumario:The title compound, C(9)H(9)N(3)O(2)S, is close to planar with an r.m.s. deviation of 0.032 Å. An intra­molecular N—H⋯N hydrogen bond closes an S(5) ring. In the crystal, mol­ecules are connected into inversion dimers of the R (2) (2)(8) type by pairs of O—H⋯O inter­actions. The dimers are further connected by pairs of N—H⋯S inter­actions, which also complete R (2) (2)(8) ring motifs. The chains of dimers are cross-linked by N—H⋯O bonds and hence R (4) (2)(28) rings are completed. Taken together, these inter­actions lead to infinite sheets propagating in the (122) plane.

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