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Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione

The title compound, C(17)H(21)NO(4), consists of substituted Meldrum’s acid with a [4-(di­ethyl­amino)­phen­yl]methyl­idene fragment attached to the fifth position. The heterocycle assumes a distorted boat conformation. The planar part of heterocycle is almost coplanar with the benzene ring due to t...

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Autores principales: Stepina, Egija, Stepanovs, Dmitrijs, Mierina, Inese, Jure, Mara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647437/
https://www.ncbi.nlm.nih.gov/pubmed/26594416
http://dx.doi.org/10.1107/S2056989015017673
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author Stepina, Egija
Stepanovs, Dmitrijs
Mierina, Inese
Jure, Mara
author_facet Stepina, Egija
Stepanovs, Dmitrijs
Mierina, Inese
Jure, Mara
author_sort Stepina, Egija
collection PubMed
description The title compound, C(17)H(21)NO(4), consists of substituted Meldrum’s acid with a [4-(di­ethyl­amino)­phen­yl]methyl­idene fragment attached to the fifth position. The heterocycle assumes a distorted boat conformation. The planar part of heterocycle is almost coplanar with the benzene ring due to the presence of a long conjugated system in the mol­ecule. This leads to the formation of C—H⋯O-type intra­molecular contacts. As a result of the absence of hydrogen-bond donors in the structure, the crystal packing is controlled by van der Waals forces and weak C—H⋯O inter­actions, which associate the mol­ecules into inversion dimers.
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spelling pubmed-46474372015-11-20 Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione Stepina, Egija Stepanovs, Dmitrijs Mierina, Inese Jure, Mara Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(17)H(21)NO(4), consists of substituted Meldrum’s acid with a [4-(di­ethyl­amino)­phen­yl]methyl­idene fragment attached to the fifth position. The heterocycle assumes a distorted boat conformation. The planar part of heterocycle is almost coplanar with the benzene ring due to the presence of a long conjugated system in the mol­ecule. This leads to the formation of C—H⋯O-type intra­molecular contacts. As a result of the absence of hydrogen-bond donors in the structure, the crystal packing is controlled by van der Waals forces and weak C—H⋯O inter­actions, which associate the mol­ecules into inversion dimers. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647437/ /pubmed/26594416 http://dx.doi.org/10.1107/S2056989015017673 Text en © Stepina et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Stepina, Egija
Stepanovs, Dmitrijs
Mierina, Inese
Jure, Mara
Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_full Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_fullStr Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_full_unstemmed Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_short Crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
title_sort crystal structure of 5-[4-(di­ethyl­amino)­benzyl­idene]-2,2-dimethyl-1,3-dioxane-4,6-dione
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647437/
https://www.ncbi.nlm.nih.gov/pubmed/26594416
http://dx.doi.org/10.1107/S2056989015017673
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