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Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol

In the title compound, C(21)H(20)N(2)O(3), the planes of the benzene ring and the naphthalene ring system are inclined to one another by 70.95°, and by 4.99 (6) and 75.93 (5)°, respectively, to the mean plane of the pyrazoline ring. The latter has an envelope conformation with the methine (CH) C ato...

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Detalles Bibliográficos
Autor principal: Koh, Dongsoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647439/
https://www.ncbi.nlm.nih.gov/pubmed/26594435
http://dx.doi.org/10.1107/S2056989015016369
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author Koh, Dongsoo
author_facet Koh, Dongsoo
author_sort Koh, Dongsoo
collection PubMed
description In the title compound, C(21)H(20)N(2)O(3), the planes of the benzene ring and the naphthalene ring system are inclined to one another by 70.95°, and by 4.99 (6) and 75.93 (5)°, respectively, to the mean plane of the pyrazoline ring. The latter has an envelope conformation with the methine (CH) C atom as the flap. There is an intra­molecular O—H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming chains along [100]. The chains are linked via C—H⋯N hydrogen bonds, forming sheets parallel to the ab plane. The sheets are linked by a series of N—H⋯π and C—H⋯π inter­actions forming a three-dimensional structure.
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spelling pubmed-46474392015-11-20 Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol Koh, Dongsoo Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(21)H(20)N(2)O(3), the planes of the benzene ring and the naphthalene ring system are inclined to one another by 70.95°, and by 4.99 (6) and 75.93 (5)°, respectively, to the mean plane of the pyrazoline ring. The latter has an envelope conformation with the methine (CH) C atom as the flap. There is an intra­molecular O—H⋯N hydrogen bond that forms an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming chains along [100]. The chains are linked via C—H⋯N hydrogen bonds, forming sheets parallel to the ab plane. The sheets are linked by a series of N—H⋯π and C—H⋯π inter­actions forming a three-dimensional structure. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647439/ /pubmed/26594435 http://dx.doi.org/10.1107/S2056989015016369 Text en © Dongsoo Koh 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Koh, Dongsoo
Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_full Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_fullStr Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_full_unstemmed Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_short Crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_sort crystal structure of 3,5-dimeth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1h-pyrazol-3-yl]phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647439/
https://www.ncbi.nlm.nih.gov/pubmed/26594435
http://dx.doi.org/10.1107/S2056989015016369
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