Cargando…
Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate
In the title compound, C(17)H(17)N(3)O(3)S, the cyclopentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thiazolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phe...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647441/ https://www.ncbi.nlm.nih.gov/pubmed/26594474 http://dx.doi.org/10.1107/S2056989015017454 |
| _version_ | 1782401099760664576 |
|---|---|
| author | Akkurt, Mehmet Smolenski, Victoria A. Mohamed, Shaaban K. Jasinski, Jerry P. Hassan, Alaa A. Albayati, Mustafa R. |
| author_facet | Akkurt, Mehmet Smolenski, Victoria A. Mohamed, Shaaban K. Jasinski, Jerry P. Hassan, Alaa A. Albayati, Mustafa R. |
| author_sort | Akkurt, Mehmet |
| collection | PubMed |
| description | In the title compound, C(17)H(17)N(3)O(3)S, the cyclopentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thiazolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phenyl ring. The molecular packing is stabilized by C—H⋯O and C—H⋯π interactions, forming a three-dimensional structure. |
| format | Online Article Text |
| id | pubmed-4647441 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-46474412015-11-20 Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate Akkurt, Mehmet Smolenski, Victoria A. Mohamed, Shaaban K. Jasinski, Jerry P. Hassan, Alaa A. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(17)H(17)N(3)O(3)S, the cyclopentane ring is disordered over two sets of sites with an occupancy ratio of 0.775 (8):0.225 (8) for the affected atoms. The thiazolidinyl ring is planar (r.m.s. deviation = 0.024 Å) and forms a dihedral angle of 65.13 (8)° with the attached phenyl ring. The molecular packing is stabilized by C—H⋯O and C—H⋯π interactions, forming a three-dimensional structure. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647441/ /pubmed/26594474 http://dx.doi.org/10.1107/S2056989015017454 Text en © Akkurt et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Akkurt, Mehmet Smolenski, Victoria A. Mohamed, Shaaban K. Jasinski, Jerry P. Hassan, Alaa A. Albayati, Mustafa R. Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_full | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_fullStr | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_full_unstemmed | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_short | Crystal structure of methyl (2Z)-2-[(2Z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| title_sort | crystal structure of methyl (2z)-2-[(2z)-2-(2-cyclopentylidenehydrazin-1-ylidene)-4-oxo-3-phenyl-1,3-thiazolidin-5-ylidene]ethanoate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647441/ https://www.ncbi.nlm.nih.gov/pubmed/26594474 http://dx.doi.org/10.1107/S2056989015017454 |
| work_keys_str_mv | AT akkurtmehmet crystalstructureofmethyl2z22z22cyclopentylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneethanoate AT smolenskivictoriaa crystalstructureofmethyl2z22z22cyclopentylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneethanoate AT mohamedshaabank crystalstructureofmethyl2z22z22cyclopentylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneethanoate AT jasinskijerryp crystalstructureofmethyl2z22z22cyclopentylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneethanoate AT hassanalaaa crystalstructureofmethyl2z22z22cyclopentylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneethanoate AT albayatimustafar crystalstructureofmethyl2z22z22cyclopentylidenehydrazin1ylidene4oxo3phenyl13thiazolidin5ylideneethanoate |