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Covalency of hydrogen bonds in liquid water can be probed by proton nuclear magnetic resonance experiments

The concept of covalency is widely used to describe the nature of intermolecular bonds, to explain their spectroscopic features and to rationalize their chemical behaviour. Unfortunately, the degree of covalency of an intermolecular bond cannot be directly measured in an experiment. Here we establis...

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Detalles Bibliográficos
Autores principales: Elgabarty, Hossam, Khaliullin, Rustam Z., Kühne, Thomas D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Pub. Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647854/
https://www.ncbi.nlm.nih.gov/pubmed/26370179
http://dx.doi.org/10.1038/ncomms9318