Attenuated Organomagnesium Activation of White Phosphorus**

Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P(4) allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2−) and [nBu(2)P(8)](2−) cluster dianions.

Detalles Bibliográficos
Autores principales: Arrowsmith, Merle, Hill, Michael S, Johnson, Andrew L, Kociok-Köhn, Gabriele, Mahon, Mary F
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648029/
https://www.ncbi.nlm.nih.gov/pubmed/26014162
http://dx.doi.org/10.1002/anie.201503065
Descripción
Sumario:Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P(4) allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2−) and [nBu(2)P(8)](2−) cluster dianions.

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