Cargando…
Attenuated Organomagnesium Activation of White Phosphorus**
Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P(4) allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2−) and [nBu(2)P(8)](2−) cluster dianions.
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648029/ https://www.ncbi.nlm.nih.gov/pubmed/26014162 http://dx.doi.org/10.1002/anie.201503065 |
_version_ | 1782401180466413568 |
---|---|
author | Arrowsmith, Merle Hill, Michael S Johnson, Andrew L Kociok-Köhn, Gabriele Mahon, Mary F |
author_facet | Arrowsmith, Merle Hill, Michael S Johnson, Andrew L Kociok-Köhn, Gabriele Mahon, Mary F |
author_sort | Arrowsmith, Merle |
collection | PubMed |
description | Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P(4) allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2−) and [nBu(2)P(8)](2−) cluster dianions. |
format | Online Article Text |
id | pubmed-4648029 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | WILEY-VCH Verlag |
record_format | MEDLINE/PubMed |
spelling | pubmed-46480292015-11-24 Attenuated Organomagnesium Activation of White Phosphorus** Arrowsmith, Merle Hill, Michael S Johnson, Andrew L Kociok-Köhn, Gabriele Mahon, Mary F Angew Chem Int Ed Engl Communications Sequential reactions between a 2,6-diisopropylphenyl-substituted β-diketiminato magnesium n-butyl derivative and P(4) allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2−) and [nBu(2)P(8)](2−) cluster dianions. WILEY-VCH Verlag 2015-06-26 2015-05-26 /pmc/articles/PMC4648029/ /pubmed/26014162 http://dx.doi.org/10.1002/anie.201503065 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Communications Arrowsmith, Merle Hill, Michael S Johnson, Andrew L Kociok-Köhn, Gabriele Mahon, Mary F Attenuated Organomagnesium Activation of White Phosphorus** |
title | Attenuated Organomagnesium Activation of White Phosphorus** |
title_full | Attenuated Organomagnesium Activation of White Phosphorus** |
title_fullStr | Attenuated Organomagnesium Activation of White Phosphorus** |
title_full_unstemmed | Attenuated Organomagnesium Activation of White Phosphorus** |
title_short | Attenuated Organomagnesium Activation of White Phosphorus** |
title_sort | attenuated organomagnesium activation of white phosphorus** |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648029/ https://www.ncbi.nlm.nih.gov/pubmed/26014162 http://dx.doi.org/10.1002/anie.201503065 |
work_keys_str_mv | AT arrowsmithmerle attenuatedorganomagnesiumactivationofwhitephosphorus AT hillmichaels attenuatedorganomagnesiumactivationofwhitephosphorus AT johnsonandrewl attenuatedorganomagnesiumactivationofwhitephosphorus AT kociokkohngabriele attenuatedorganomagnesiumactivationofwhitephosphorus AT mahonmaryf attenuatedorganomagnesiumactivationofwhitephosphorus |