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Reduction of Carbon Dioxide to Formate at Low Overpotential Using a Superbase Ionic Liquid

A new low-energy pathway is reported for the electrochemical reduction of CO(2) to formate and syngas at low overpotentials, utilizing a reactive ionic liquid as the solvent. The superbasic tetraalkyl phosphonium ionic liquid [P(66614)][124Triz] is able to chemisorb CO(2) through equimolar binding o...

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Detalles Bibliográficos
Autores principales:	Hollingsworth, Nathan, Taylor, S F Rebecca, Galante, Miguel T, Jacquemin, Johan, Longo, Claudia, Holt, Katherine B, de Leeuw, Nora H, Hardacre, Christopher
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4648032/ https://www.ncbi.nlm.nih.gov/pubmed/26403938 http://dx.doi.org/10.1002/anie.201507629

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