Electrochemistry in supercritical fluids

A wide range of supercritical fluids (SCFs) have been studied as solvents for electrochemistry with carbon dioxide and hydrofluorocarbons (HFCs) being the most extensively studied. Recent advances have shown that it is possible to get well-resolved voltammetry in SCFs by suitable choice of the condi...

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Detalles Bibliográficos
Autores principales: Branch, Jack A., Bartlett, Philip N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2015
Materias:
Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4650015/
https://www.ncbi.nlm.nih.gov/pubmed/26574527
http://dx.doi.org/10.1098/rsta.2015.0007
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author Branch, Jack A.
Bartlett, Philip N.
author_facet Branch, Jack A.
Bartlett, Philip N.
author_sort Branch, Jack A.
collection PubMed
description A wide range of supercritical fluids (SCFs) have been studied as solvents for electrochemistry with carbon dioxide and hydrofluorocarbons (HFCs) being the most extensively studied. Recent advances have shown that it is possible to get well-resolved voltammetry in SCFs by suitable choice of the conditions and the electrolyte. In this review, we discuss the voltammetry obtained in these systems, studies of the double-layer capacitance, work on the electrodeposition of metals into high aspect ratio nanopores and the use of metallocenes as redox probes and standards in both supercritical carbon dioxide–acetonitrile and supercritical HFCs.
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spelling pubmed-46500152015-12-28 Electrochemistry in supercritical fluids Branch, Jack A. Bartlett, Philip N. Philos Trans A Math Phys Eng Sci Articles A wide range of supercritical fluids (SCFs) have been studied as solvents for electrochemistry with carbon dioxide and hydrofluorocarbons (HFCs) being the most extensively studied. Recent advances have shown that it is possible to get well-resolved voltammetry in SCFs by suitable choice of the conditions and the electrolyte. In this review, we discuss the voltammetry obtained in these systems, studies of the double-layer capacitance, work on the electrodeposition of metals into high aspect ratio nanopores and the use of metallocenes as redox probes and standards in both supercritical carbon dioxide–acetonitrile and supercritical HFCs. The Royal Society Publishing 2015-12-28 /pmc/articles/PMC4650015/ /pubmed/26574527 http://dx.doi.org/10.1098/rsta.2015.0007 Text en © 2015 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.
spellingShingle Articles
Branch, Jack A.
Bartlett, Philip N.
Electrochemistry in supercritical fluids
title Electrochemistry in supercritical fluids
title_full Electrochemistry in supercritical fluids
title_fullStr Electrochemistry in supercritical fluids
title_full_unstemmed Electrochemistry in supercritical fluids
title_short Electrochemistry in supercritical fluids
title_sort electrochemistry in supercritical fluids
topic Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4650015/
https://www.ncbi.nlm.nih.gov/pubmed/26574527
http://dx.doi.org/10.1098/rsta.2015.0007
work_keys_str_mv AT branchjacka electrochemistryinsupercriticalfluids
AT bartlettphilipn electrochemistryinsupercriticalfluids

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