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Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne

The title compound, C(34)H(37)N, is a pyrene derivative in which the pyrene ring system is linked to an ethyl­cyclo­hexane unit which, in turn, carries a [4-(di­methyl­amino)­phen­yl]ethyl substituent in the para position. The central cyclo­hexane ring has a chair conformation, with the exocyclic C—...

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Detalles Bibliográficos
Autores principales: Thekku Veedu, Sreevidya, Techert, Simone
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4650969/
https://www.ncbi.nlm.nih.gov/pubmed/26594590
http://dx.doi.org/10.1107/S2056989015013729
Descripción
Sumario:The title compound, C(34)H(37)N, is a pyrene derivative in which the pyrene ring system is linked to an ethyl­cyclo­hexane unit which, in turn, carries a [4-(di­methyl­amino)­phen­yl]ethyl substituent in the para position. The central cyclo­hexane ring has a chair conformation, with the exocyclic C—C bonds in equatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation = 0.038 (4) Å] by 14.84 (15)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)].