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Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne

The title compound, C(34)H(37)N, is a pyrene derivative in which the pyrene ring system is linked to an ethyl­cyclo­hexane unit which, in turn, carries a [4-(di­methyl­amino)­phen­yl]ethyl substituent in the para position. The central cyclo­hexane ring has a chair conformation, with the exocyclic C—...

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Detalles Bibliográficos
Autores principales: Thekku Veedu, Sreevidya, Techert, Simone
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4650969/
https://www.ncbi.nlm.nih.gov/pubmed/26594590
http://dx.doi.org/10.1107/S2056989015013729
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author Thekku Veedu, Sreevidya
Techert, Simone
author_facet Thekku Veedu, Sreevidya
Techert, Simone
author_sort Thekku Veedu, Sreevidya
collection PubMed
description The title compound, C(34)H(37)N, is a pyrene derivative in which the pyrene ring system is linked to an ethyl­cyclo­hexane unit which, in turn, carries a [4-(di­methyl­amino)­phen­yl]ethyl substituent in the para position. The central cyclo­hexane ring has a chair conformation, with the exocyclic C—C bonds in equatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation = 0.038 (4) Å] by 14.84 (15)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)].
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spelling pubmed-46509692015-11-20 Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne Thekku Veedu, Sreevidya Techert, Simone Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(34)H(37)N, is a pyrene derivative in which the pyrene ring system is linked to an ethyl­cyclo­hexane unit which, in turn, carries a [4-(di­methyl­amino)­phen­yl]ethyl substituent in the para position. The central cyclo­hexane ring has a chair conformation, with the exocyclic C—C bonds in equatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation = 0.038 (4) Å] by 14.84 (15)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)]. International Union of Crystallography 2015-07-31 /pmc/articles/PMC4650969/ /pubmed/26594590 http://dx.doi.org/10.1107/S2056989015013729 Text en © Thekku Veedu and Techert 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Thekku Veedu, Sreevidya
Techert, Simone
Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
title Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
title_full Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
title_fullStr Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
title_full_unstemmed Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
title_short Crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
title_sort crystal structure of trans-1-{2-[4-(di­methyl­amino)­phen­yl]eth­yl}-4-[2-(pyren-1-yl)eth­yl]cyclo­hexa­ne
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4650969/
https://www.ncbi.nlm.nih.gov/pubmed/26594590
http://dx.doi.org/10.1107/S2056989015013729
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AT techertsimone crystalstructureoftrans124dimethylaminophenylethyl42pyren1ylethylcyclohexane