Fe(II)/Et(3)N-Relay-catalyzed domino reaction of isoxazoles with imidazolium salts in the synthesis of methyl 4-imidazolylpyrrole-2-carboxylates, its ylide and betaine derivatives

A simple approach was developed for the synthesis of methyl 4-imidazolylpyrrole-2-carboxylates from easily available compounds, 5-methoxyisoxazoles and phenacylimidazolium salts under hybrid Fe(II)/Et(3)N relay catalysis. The products were easily transformed into the corresponding 3-(5-methoxycarbon...

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Detalles Bibliográficos
Autores principales: Galenko, Ekaterina E, Tomashenko, Olesya A, Khlebnikov, Alexander F, Novikov, Mikhail S, Panikorovskii, Taras L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660897/
https://www.ncbi.nlm.nih.gov/pubmed/26664593
http://dx.doi.org/10.3762/bjoc.11.189

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