[2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties

The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselec...

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Detalles Bibliográficos
Autores principales: Sarbu, Laura G, Bahrin, Lucian G, Jones, Peter G, Birsa, Lucian M, Hopf, Henning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660956/
https://www.ncbi.nlm.nih.gov/pubmed/26664611
http://dx.doi.org/10.3762/bjoc.11.207
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author Sarbu, Laura G
Bahrin, Lucian G
Jones, Peter G
Birsa, Lucian M
Hopf, Henning
author_facet Sarbu, Laura G
Bahrin, Lucian G
Jones, Peter G
Birsa, Lucian M
Hopf, Henning
author_sort Sarbu, Laura G
collection PubMed
description The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselective bromination of 4-acetyl[2.2]paracyclophane, then through the corresponding dithiocarbamates and 1,3-dithiolium salts.
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spelling pubmed-46609562015-12-09 [2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties Sarbu, Laura G Bahrin, Lucian G Jones, Peter G Birsa, Lucian M Hopf, Henning Beilstein J Org Chem Letter The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselective bromination of 4-acetyl[2.2]paracyclophane, then through the corresponding dithiocarbamates and 1,3-dithiolium salts. Beilstein-Institut 2015-10-15 /pmc/articles/PMC4660956/ /pubmed/26664611 http://dx.doi.org/10.3762/bjoc.11.207 Text en Copyright © 2015, Sarbu et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Sarbu, Laura G
Bahrin, Lucian G
Jones, Peter G
Birsa, Lucian M
Hopf, Henning
[2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
title [2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
title_full [2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
title_fullStr [2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
title_full_unstemmed [2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
title_short [2.2]Paracyclophane derivatives containing tetrathiafulvalene moieties
title_sort [2.2]paracyclophane derivatives containing tetrathiafulvalene moieties
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660956/
https://www.ncbi.nlm.nih.gov/pubmed/26664611
http://dx.doi.org/10.3762/bjoc.11.207
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