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Convenient preparation of high molecular weight poly(dimethylsiloxane) using thermally latent NHC-catalysis: a structure-activity correlation

The polymerization of octamethylcyclotetrasiloxane (D(4)) is investigated using several five-, six- and seven-membered N-heterocyclic carbenes (NHCs). The catalysts are delivered in situ from thermally susceptible CO(2) adducts. It is demonstrated that the polymerization can be triggered from a late...

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Detalles Bibliográficos
Autores principales:	Naumann, Stefan, Klein, Johannes, Wang, Dongren, Buchmeiser, Michael R
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660969/ https://www.ncbi.nlm.nih.gov/pubmed/26664650 http://dx.doi.org/10.3762/bjoc.11.246

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