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Coupling of α,α-difluoro-substituted organozinc reagents with 1-bromoalkynes

α,α-Difluoro-substituted organozinc reagents generated from conventional organozinc compounds and difluorocarbene couple with 1-bromoalkynes affording gem-difluorinated alkynes. The cross-coupling proceeds in the presence of catalytic amounts of copper iodide in dimethylformamide under ligand-free c...

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Detalles Bibliográficos
Autores principales:	Zemtsov, Artem A, Volodin, Alexander D, Levin, Vitalij V, Struchkova, Marina I, Dilman, Alexander D
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Letter
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660974/ https://www.ncbi.nlm.nih.gov/pubmed/26664635 http://dx.doi.org/10.3762/bjoc.11.231

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