Photoinduced 1,2,3,4-tetrahydropyridine ring conversions

Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome o...

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Detalles Bibliográficos
Autores principales: Turovska, Baiba, Lund, Henning, Lūsis, Viesturs, Lielpētere, Anna, Liepiņš, Edvards, Beljakovs, Sergejs, Goba, Inguna, Stradiņš, Jānis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660982/
https://www.ncbi.nlm.nih.gov/pubmed/26664638
http://dx.doi.org/10.3762/bjoc.11.234
Descripción
Sumario:Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O(2). In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions.

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