Photoinduced 1,2,3,4-tetrahydropyridine ring conversions

Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome o...

Descripción completa

Detalles Bibliográficos
Autores principales: Turovska, Baiba, Lund, Henning, Lūsis, Viesturs, Lielpētere, Anna, Liepiņš, Edvards, Beljakovs, Sergejs, Goba, Inguna, Stradiņš, Jānis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660982/
https://www.ncbi.nlm.nih.gov/pubmed/26664638
http://dx.doi.org/10.3762/bjoc.11.234
_version_ 1782402913171144704
author Turovska, Baiba
Lund, Henning
Lūsis, Viesturs
Lielpētere, Anna
Liepiņš, Edvards
Beljakovs, Sergejs
Goba, Inguna
Stradiņš, Jānis
author_facet Turovska, Baiba
Lund, Henning
Lūsis, Viesturs
Lielpētere, Anna
Liepiņš, Edvards
Beljakovs, Sergejs
Goba, Inguna
Stradiņš, Jānis
author_sort Turovska, Baiba
collection PubMed
description Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O(2). In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions.
format Online
Article
Text
id pubmed-4660982
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-46609822015-12-09 Photoinduced 1,2,3,4-tetrahydropyridine ring conversions Turovska, Baiba Lund, Henning Lūsis, Viesturs Lielpētere, Anna Liepiņš, Edvards Beljakovs, Sergejs Goba, Inguna Stradiņš, Jānis Beilstein J Org Chem Letter Stable heterocyclic hydroperoxide can be easily prepared as a product of fast oxidation of a 1,2,3,4-tetrahydropyridine by (3)O(2) if the solution is exposed to sunlight. The driving force for the photoinduced electron transfer is calculated from electrochemical and spectroscopic data. The outcome of the reaction depends on the light intensity and the concentration of O(2). In the solid state the heterocyclic hydroperoxide is stable; in solution it is involved in further reactions. Beilstein-Institut 2015-11-11 /pmc/articles/PMC4660982/ /pubmed/26664638 http://dx.doi.org/10.3762/bjoc.11.234 Text en Copyright © 2015, Turovska et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Turovska, Baiba
Lund, Henning
Lūsis, Viesturs
Lielpētere, Anna
Liepiņš, Edvards
Beljakovs, Sergejs
Goba, Inguna
Stradiņš, Jānis
Photoinduced 1,2,3,4-tetrahydropyridine ring conversions
title Photoinduced 1,2,3,4-tetrahydropyridine ring conversions
title_full Photoinduced 1,2,3,4-tetrahydropyridine ring conversions
title_fullStr Photoinduced 1,2,3,4-tetrahydropyridine ring conversions
title_full_unstemmed Photoinduced 1,2,3,4-tetrahydropyridine ring conversions
title_short Photoinduced 1,2,3,4-tetrahydropyridine ring conversions
title_sort photoinduced 1,2,3,4-tetrahydropyridine ring conversions
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4660982/
https://www.ncbi.nlm.nih.gov/pubmed/26664638
http://dx.doi.org/10.3762/bjoc.11.234
work_keys_str_mv AT turovskabaiba photoinduced1234tetrahydropyridineringconversions
AT lundhenning photoinduced1234tetrahydropyridineringconversions
AT lusisviesturs photoinduced1234tetrahydropyridineringconversions
AT lielpetereanna photoinduced1234tetrahydropyridineringconversions
AT liepinsedvards photoinduced1234tetrahydropyridineringconversions
AT beljakovssergejs photoinduced1234tetrahydropyridineringconversions
AT gobainguna photoinduced1234tetrahydropyridineringconversions
AT stradinsjanis photoinduced1234tetrahydropyridineringconversions

Ejemplares similares