Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis

Three new Au(I) complexes of the formula [Au(NHC)(NTf(2))] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the ‘ITent’ (‘Tent’ for ‘tentacular’) family of NHC derivatives. The effect of these ligan...

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Detalles Bibliográficos
Autores principales: Collado, Alba, Patrick, Scott R, Gasperini, Danila, Meiries, Sebastien, Nolan, Steven P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661005/
https://www.ncbi.nlm.nih.gov/pubmed/26664600
http://dx.doi.org/10.3762/bjoc.11.196
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author Collado, Alba
Patrick, Scott R
Gasperini, Danila
Meiries, Sebastien
Nolan, Steven P
author_facet Collado, Alba
Patrick, Scott R
Gasperini, Danila
Meiries, Sebastien
Nolan, Steven P
author_sort Collado, Alba
collection PubMed
description Three new Au(I) complexes of the formula [Au(NHC)(NTf(2))] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the ‘ITent’ (‘Tent’ for ‘tentacular’) family of NHC derivatives. The effect of these ligands in gold-promoted transformations has been investigated.
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spelling pubmed-46610052015-12-09 Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis Collado, Alba Patrick, Scott R Gasperini, Danila Meiries, Sebastien Nolan, Steven P Beilstein J Org Chem Full Research Paper Three new Au(I) complexes of the formula [Au(NHC)(NTf(2))] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the ‘ITent’ (‘Tent’ for ‘tentacular’) family of NHC derivatives. The effect of these ligands in gold-promoted transformations has been investigated. Beilstein-Institut 2015-10-02 /pmc/articles/PMC4661005/ /pubmed/26664600 http://dx.doi.org/10.3762/bjoc.11.196 Text en Copyright © 2015, Collado et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Collado, Alba
Patrick, Scott R
Gasperini, Danila
Meiries, Sebastien
Nolan, Steven P
Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
title Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
title_full Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
title_fullStr Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
title_full_unstemmed Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
title_short Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis
title_sort influence of bulky yet flexible n-heterocyclic carbene ligands in gold catalysis
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4661005/
https://www.ncbi.nlm.nih.gov/pubmed/26664600
http://dx.doi.org/10.3762/bjoc.11.196
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