Mechanistic Insights into Two-Phase Radical C–H Arylations

[Image: see text] Kinetic, spectroscopic, and computational studies of radical C–H arylations highlight the interplay between chemical and physical rate processes in these multiphase reactions. Anomalous concentration dependences observed here may be reconciled by considering the role of phase trans...

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Detalles Bibliográficos
Autores principales: Baxter, Ryan D., Liang, Yong, Hong, Xin, Brown, Timothy A., Zare, Richard N., Houk, K. N., Baran, Phil S., Blackmond, Donna G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4665085/
https://www.ncbi.nlm.nih.gov/pubmed/26640819
http://dx.doi.org/10.1021/acscentsci.5b00332
Descripción
Sumario:[Image: see text] Kinetic, spectroscopic, and computational studies of radical C–H arylations highlight the interplay between chemical and physical rate processes in these multiphase reactions. Anomalous concentration dependences observed here may be reconciled by considering the role of phase transfer processes that mediate concentrations in each phase. In addition, understanding interactions through phase boundaries enables their use in optimization of reaction performance.

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