Cargando…
Mechanistic Insights into Two-Phase Radical C–H Arylations
[Image: see text] Kinetic, spectroscopic, and computational studies of radical C–H arylations highlight the interplay between chemical and physical rate processes in these multiphase reactions. Anomalous concentration dependences observed here may be reconciled by considering the role of phase trans...
Autores principales: | Baxter, Ryan D., Liang, Yong, Hong, Xin, Brown, Timothy A., Zare, Richard N., Houk, K. N., Baran, Phil S., Blackmond, Donna G. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2015
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4665085/ https://www.ncbi.nlm.nih.gov/pubmed/26640819 http://dx.doi.org/10.1021/acscentsci.5b00332 |
Ejemplares similares
-
Rational
Ligand Design for the Arylation of Hindered
Primary Amines Guided by Reaction Progress Kinetic Analysis
por: Ruiz-Castillo, Paula, et al.
Publicado: (2015) -
Mechanistic insight into the effects of Aryl Hydrocarbon Receptor activation on osteogenic differentiation
por: Yun, Chawon, et al.
Publicado: (2017) -
Iron‐Electrocatalyzed C−H Arylations: Mechanistic Insights into Oxidation‐Induced Reductive Elimination for Ferraelectrocatalysis
por: Zhu, Cuiju, et al.
Publicado: (2019) -
Competing Pathways in O‐Arylations with Diaryliodonium Salts: Mechanistic Insights
por: Stridfeldt, Elin, et al.
Publicado: (2017) -
Exploring the Chemoselectivity towards Cysteine Arylation by Cyclometallated Au(III) Compounds: New Mechanistic Insights
por: Thomas, Sophie R., et al.
Publicado: (2020)