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Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates**
Fe(III)–hypohalite complexes have been implicated in a wide range of important enzyme-catalyzed halogenation reactions including the biosynthesis of natural products and antibiotics and post-translational modification of proteins. The absence of spectroscopic data on such species precludes their ide...
Autores principales: | Draksharapu, Apparao, Angelone, Davide, Quesne, Matthew G, Padamati, Sandeep K, Gómez, Laura, Hage, Ronald, Costas, Miquel, Browne, Wesley R, de Visser, Sam P |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4670478/ https://www.ncbi.nlm.nih.gov/pubmed/25663379 http://dx.doi.org/10.1002/anie.201411995 |
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