Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates**

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Fe(III)–hypohalite complexes have been implicated in a wide range of important enzyme-catalyzed halogenation reactions including the biosynthesis of natural products and antibiotics and post-translational modification of proteins. The absence of spectroscopic data on such species precludes their ide...

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Detalles Bibliográficos
Autores principales: Draksharapu, Apparao, Angelone, Davide, Quesne, Matthew G, Padamati, Sandeep K, Gómez, Laura, Hage, Ronald, Costas, Miquel, Browne, Wesley R, de Visser, Sam P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4670478/
https://www.ncbi.nlm.nih.gov/pubmed/25663379
http://dx.doi.org/10.1002/anie.201411995
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