Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**

ABSTRACT: CHECK M(ETAL)ATE: The chessboard and the figures represent a special reaction in which different low-polarity metals can metalate arenes directly when they are brought into the right position. In a combination of queen (sodium) and knight (chromium or iron), it is possible for the knight (...

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Autores principales: Alborés, Pablo, Carrella, Luca M, Clegg, William, García-Álvarez, Pablo, Kennedy, Alan R, Klett, Jan, Mulvey, Robert E, Rentschler, Eva, Russo, Luca
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2009
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4670709/
https://www.ncbi.nlm.nih.gov/pubmed/19156782
http://dx.doi.org/10.1002/anie.200805566
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author Alborés, Pablo
Carrella, Luca M
Clegg, William
García-Álvarez, Pablo
Kennedy, Alan R
Klett, Jan
Mulvey, Robert E
Rentschler, Eva
Russo, Luca
author_facet Alborés, Pablo
Carrella, Luca M
Clegg, William
García-Álvarez, Pablo
Kennedy, Alan R
Klett, Jan
Mulvey, Robert E
Rentschler, Eva
Russo, Luca
author_sort Alborés, Pablo
collection PubMed
description ABSTRACT: CHECK M(ETAL)ATE: The chessboard and the figures represent a special reaction in which different low-polarity metals can metalate arenes directly when they are brought into the right position. In a combination of queen (sodium) and knight (chromium or iron), it is possible for the knight (usually the weaker piece) to make a direct deadly hit on the king (benzene) in this game of elemental chess.
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spelling pubmed-46707092015-12-15 Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes** Alborés, Pablo Carrella, Luca M Clegg, William García-Álvarez, Pablo Kennedy, Alan R Klett, Jan Mulvey, Robert E Rentschler, Eva Russo, Luca Angew Chem Int Ed Engl Communications ABSTRACT: CHECK M(ETAL)ATE: The chessboard and the figures represent a special reaction in which different low-polarity metals can metalate arenes directly when they are brought into the right position. In a combination of queen (sodium) and knight (chromium or iron), it is possible for the knight (usually the weaker piece) to make a direct deadly hit on the king (benzene) in this game of elemental chess. WILEY-VCH Verlag 2009-04-20 2009-01-20 /pmc/articles/PMC4670709/ /pubmed/19156782 http://dx.doi.org/10.1002/anie.200805566 Text en Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Communications
Alborés, Pablo
Carrella, Luca M
Clegg, William
García-Álvarez, Pablo
Kennedy, Alan R
Klett, Jan
Mulvey, Robert E
Rentschler, Eva
Russo, Luca
Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**
title Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**
title_full Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**
title_fullStr Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**
title_full_unstemmed Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**
title_short Direct C–H Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes**
title_sort direct c–h metalation with chromium(ii) and iron(ii): transition-metal host / benzenediide guest magnetic inverse-crown complexes**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4670709/
https://www.ncbi.nlm.nih.gov/pubmed/19156782
http://dx.doi.org/10.1002/anie.200805566
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