Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes

The first examples of pyrazine-based gold(iii) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delaye...

Descripción completa

Detalles Bibliográficos
Autores principales: Fernandez-Cestau, Julio, Bertrand, Benoît, Blaya, Maria, Jones, Garth A., Penfold, Thomas J., Bochmann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4672750/
https://www.ncbi.nlm.nih.gov/pubmed/26425736
http://dx.doi.org/10.1039/c5cc07523h
_version_ 1782404626318884864
author Fernandez-Cestau, Julio
Bertrand, Benoît
Blaya, Maria
Jones, Garth A.
Penfold, Thomas J.
Bochmann, Manfred
author_facet Fernandez-Cestau, Julio
Bertrand, Benoît
Blaya, Maria
Jones, Garth A.
Penfold, Thomas J.
Bochmann, Manfred
author_sort Fernandez-Cestau, Julio
collection PubMed
description The first examples of pyrazine-based gold(iii) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF).
format Online
Article
Text
id pubmed-4672750
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-46727502015-12-21 Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes Fernandez-Cestau, Julio Bertrand, Benoît Blaya, Maria Jones, Garth A. Penfold, Thomas J. Bochmann, Manfred Chem Commun (Camb) Chemistry The first examples of pyrazine-based gold(iii) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF). Royal Society of Chemistry 2015-11-10 2015-12-04 /pmc/articles/PMC4672750/ /pubmed/26425736 http://dx.doi.org/10.1039/c5cc07523h Text en This journal is © The Royal Society of Chemistry 2015 https://creativecommons.org/licenses/by/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Fernandez-Cestau, Julio
Bertrand, Benoît
Blaya, Maria
Jones, Garth A.
Penfold, Thomas J.
Bochmann, Manfred
Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
title Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
title_full Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
title_fullStr Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
title_full_unstemmed Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
title_short Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
title_sort synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4672750/
https://www.ncbi.nlm.nih.gov/pubmed/26425736
http://dx.doi.org/10.1039/c5cc07523h
work_keys_str_mv AT fernandezcestaujulio synthesisandluminescencemodulationofpyrazinebasedgoldiiipincercomplexes
AT bertrandbenoit synthesisandluminescencemodulationofpyrazinebasedgoldiiipincercomplexes
AT blayamaria synthesisandluminescencemodulationofpyrazinebasedgoldiiipincercomplexes
AT jonesgartha synthesisandluminescencemodulationofpyrazinebasedgoldiiipincercomplexes
AT penfoldthomasj synthesisandluminescencemodulationofpyrazinebasedgoldiiipincercomplexes
AT bochmannmanfred synthesisandluminescencemodulationofpyrazinebasedgoldiiipincercomplexes

Ejemplares similares